We have two hours in Pienza. Palazzo Piccolomini is closed on the Monday of our visit. We plan a walk along the wall to take in the VIEW of the Valley d'Orcia.
Pienza is so small, you won't be missing any streets, you'll cover them in two hours (does it include lunch?) Definitely the main square and the street that runs behind the duomo (if I remember correctly, the Via dell'Amore (Way of Love)) has the stupendous views of the Val d'Orcia.
If you want great views of Pienza itself, you have to drive down from Pienza to Monticchielo and then look back up
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