Most definitely! Most restaurants will also have beer options, although they might not be as varied and wide a choice as the wine list. Over all of Italy, there is growing interest in artisan and brewing beers so you'll be surprised. I've been to a few new places in Florence which have made it part of their special offerings to have a variety of beers from tap to try out. In Florence, I'm thinking in particular of the pizzeria Berberè in Oltrarno (which opened last fall but had really slow service when we tried it out in October). -
In Greve in Chianti, there is a whole shop dedicated to beers - http://www.labirrotecadigreve.it/
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