Cinquale as in the one on the Versilia coast between Forte dei Marmi and Marina di Massa?
If that is the case, then I recommend either taking a BUS to the train stations in either Forte dei Marmi or in Massa and heading to Florence OR
takking the E1 bus from Forte dei Marmi or Marina di Massa to Florence - you can see the bus schedules here: http://www.lucca.cttnord.it/Linee_e_...raurbane/L/461
I suppose you are then spending the night in Florence before heading to Volterra?
Not easy as it is in the province of Pisa but you're starting in Florence and passing through the province of Siena.
To get to Volterra:
1. go to Colle Val d'Elsa (from Florence you need bus 131O R - http://www.tiemmespa.it/index.php/Vi...na/Extraurbano
it passes through Poggibonsi
2. then catch CPT bus to Volterra - timetable for bus 770 here:
http://www.cpt.pisa.it/orari/extra/linea770.htm
It isn't easy to get back to Pisa direct from Volterra, you need to first go to Pondera:
http://www.cpt.pisa.it/orari/extra/linea500.htm
and from there either bus (190) or train to Pisa and then back to Cinquale.
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