Ciao Ricchese,
The Capalbio Stazione FS (train station) is 10km from Capalbio town (high up on a hill). You can get there from a bus from one to the other, you just have to plan to be at Capalbio Scalo in time to catch the various ones through the day:
6.43am - 8.48am - 10.06am - 12.30pm - 1.55pm - 5.54pm Monday through Saturdays. Seems no buses on Sundays.(
http://www.tiemmespa.it/var/ezdemo_s...05ad5141c1.pdf)
Note that any stop marked with FS usually means train station as it means Ferrovie Stato in Italian.
Since the bus line also starts in or passes through Orbetello FS, you can also choose to catch the same bus earlier there (just one bus seems to not start in Orbetello). It is a bit to the north of Capalbio.
While in Capalbio, you'll need to sit tight unless you can make the bus schedule work for you. To be honest, it isn't a great base if you don't have a car but the town is quite charming.... it comes alive in the evenings when the restaurants get full of people that have been at the beach all day. In the day, it is pretty quiet.
From the Capalbio train station, you should be able to take trains back to Grosseto to then continue on to Siena and from Siena either take train or bus to Pisa (bus passes through Florence - have you already been?).
You can check all timetables on
www.trenitalia.com for each leg of your trip --- but if you also search for each leg on Google Maps and then click on the "public transport" tab, you should also see a mix of solutions that have train and bus as well. I would suggest you try Google Maps first

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